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Overview: With the development of economy, human demands for chemical materials are increasing. Although these chemical materials provide great convenience and improvement to our daily lives, gas leakage accidents in various fields happen frequently. Leakage of the commonly used flammable and explosive gases such as liquefied petroleum gas, methane and vinyl chloride may cause explosions or fires. Gas leakage accidents not only cause huge economic losses, but also can cause casualties. In addition, some non-toxic, odorless and seemingly harmless gases can also cause great harm to the environment. For example, SF6 gas, which is commonly used in power systems, and gases such as CO2 emitted in production will cause the greenhouse effect, resulting global warming. Therefore, developing gas detection technology that can achieve rapid, qualitative and quantitative identification and detection of harmful gases in various scenarios has become an urgent problem for researchers. With the development of spectral imaging technology, the spectroscopy method develops rapidly. Compared with the traditional gas detection method, the spectroscopy method does not require sample preparation, and is fast, non-invasive, highly-efficient and dynamic, thus suitable for rapid and continuous detection in various fields. Accordingly, the spectroscopy method has become a hot spot of research and application in various countries.
This paper first introduces the theoretical foundation of optical gas detection technology, and then reviews the working principle and application of various optical detection technologies for typical gases according to active and passive detection. Active detection methods include tunable diode laser absorption spectroscopy (TDLAS), differential absorption LiDAR (DIAL), differential optical absorption spectroscopy (DOAS), etc. Passive detection methods include remote sensing Fourier transform infrared spectroscopy (RS-FTIR) and spectral imaging (SI). This paper focuses on the applications of optical gas detection methods mentioned above. In order to facilitate a deeper understanding of the application fields of each technology, we have detailed the types of gases, accuracy, detection limits, volume and cost that can be detected in each technical, and the latest application results of each technology are introduced in detail. Using these gas detection technologies, continuous and real-time monitoring with long distance and high sensitivity for dozens of gases have been achieved, measurements of composition, concentration, temperature and other parameters of gases in a variety of scenarios have been realized, thus effectively reducing the appearances of dangerous accidents. The future development tendency of optical gas detection technologies is prospected after summarizing and analyzing the existing technologies and their problems.
Absorption line of common gas molecules[5]
Principle of spectral absorption
The multiplayer model of passive remote
Three-layer model of passive remote sensing
(a) Structure of the near-infrared C2H2 detection system; (b) Curve of the 2f signal's amplitude versus C2H2 concentration; (c) Long-term monitoring on the prepared standard 1000 ppm C2H2 sample[19]
Principle of differential absorption LiDAR system
System schematic diagram and measurement results. (a) Schematic of SO2/NO2 DIAL system; (b) The evolution diagram of SO2 measured by SO2/NO2 DIAL; (c) The evolution diagram of NO2 measured by SO2/NO2 DIAL[25]
Laser radar measuring device based on upconversion detector[30
Function diagram of differential optical absorption spectroscopy system
Measurement method and results of NO2. (a) Map of Bucharest with an overview of the measurements; Blue lines show the flight tracks, Circles and triangles mark the measurement locations; (b) Vertical column densities measured on first day; (c) Vertical column densities measured on second day[34]
Principle of passive remote sensing of FTIR
Integrative investigations of near-ground surface atmospheric CO2 conditions. (a) Application of the vehicle-mounted OP-FTIR spectrometer in different land; (b) Polar plot of the horizontal distribution of path integrated CO2 concentration measured at the southwestern point; (c) Polar plot of the horizontal distribution of path integrated CO2 concentration measured at the central point[50]
Principle of spectral imaging technology and schematic diagram of 3D data cubes
(a) Gas imaging spectrometer and its application of FIRST; (b) Gas imaging spectrometer and its application of Sherlock VOC; (c) Gas imaging spectrometer and its application of AIRIS-WAD
Experimental set-up and its result. (a) Hyperspectral imager of HI 90; (b)~(c) Detection scene and result of methane; (d)~(e) Detection scene and result of SF6[61]
Payloads configuration and spectral characteristics of GF-5. (a) Payloads configuration of GF-5 satellite; (b) Spectral characteristics of earth imaging instrument for GF-5; (c) Spectral characteristics of atmosphere sounding for GF-5[69]