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Laser direct writing (LDW) is a highly efficient and scalable method to prepare flexible electronic devices. The LDW can obtain the electronics devices by simple operation processes, which has been applied on energy storage devices, stress/strain sensors, gas sensors etc. During the LDW process, the laser works as a heat source to directly generate porous carbon on flexible substrates. In this study, LDW is developed to fabricate flexible antenna-based sensors on polyimide (PI) film. PI is a type of polymer with imide groups as its characteristic structure, which possesses excellent dielectric properties and is applied as the functional materials in many fields. The carbonized PI has good conductivity and great adhesion to the substrate, which could be used as the active material for antenna. Antenna is the component used to transmit and emit electromagnetic waves, and its performance is mainly determined by its structure and material. The variation of environmental conditions such as humidity and temperature as well as the applied strain will lead to the changes of the resonant frequency, reflection coefficient and other electromagnetic parameters of antenna. Currently, antenna-based sensors are typically fabricated by lithography or printing technology, which is either complicated or time-consuming. The resonance frequency of the LDW-generated antenna sensor changes upon the variation of applied strain and environmental humidity. The carbonized polyimide presents porous and stacked carbon structures. In addition, the electrical properties of carbonized PI are excellent with the resistivity of about 2.4 Ω•cm. The carbonized PI is a good candidate for antenna sensor because of the structures and the electrical properties, which facilitate strain sensing and make the antenna have low loss, respectively. The sensitivities of the devices in response to applied strain and humidity are −8.943 kHz/με and −6.45 MHz/RH%, respectively. In addition, the proposed antenna sensor can resist the temperature interference, and the performance of the antenna sensor hardly changes under different room temperatures from 25 ℃ to 55 ℃. Furthermore, in order to demonstrate the stability of the LDW-generated antenna sensor, we measured the performance of antenna sensor after 1 month and 4 months. The sensitivity and the resonance frequency of antenna sensor have almost no change. As for the repeatability of LDW-generated antenna, we repeated the fabrication processes under the same laser power and laser speed, the experiment results show that the antenna sensors have the excellent repeatability because the sensitivity and the resonance frequency of antenna sensors are almost identical. Overall, the flexible antenna sensor prepared by the LDW provides a new possibility for the application of structural health monitoring.
(a) The fabrication process of laser direct writing; (b) The schematic diagram of antenna measurement
(a) The electronical property of polyimide after carbonization under different laser power and laser speed; (b) The Raman curve; (c), (d) The SEM and (e), (f) the TEM of carbonized polyimide film
(a) The curves of the refection coefficient (S11) for the circle antenna sensor at different applied strain; (b) The schematic diagram of antenna sensor for measuring the strain of metal sample and the curves of the refection coefficient (S11); (c) The fitting curves of circle antenna sensor by experiments and simulation; (d) The curves of the refection coefficient (S11) for the circle antenna sensor at different times and the curves of the refection coefficient (S11) for different circle antenna sensors; (e) The resonance frequencies and sensitivities of the antenna sensor at different times; (f) The resonance frequencies and sensitivities of different samples
(a) The curves of the refection coefficient (S11) for the circle antenna sensor at different humidity; (b) The resonance frequency shift of the circle antenna at different humidity.
(a) The curves of the refection coefficient (S11) for the circle antenna sensor at different temperature; (b) The resonance frequency shift of the circle antenna at different temperature